TE0722 does boot always from SPI Flash, changing the Boot Mode is not possible from any of the accessible connector or switches.
If TE0722 SPI Flash is accidentally programmed with Boot.bin that includes a FSBL that is not adapter for TE0722 DDR-less operation then ZYNQ Boot-ROM will not release JTAG DAP, and access to JTAG including reprogramming the SPI Flash is no longer possible.
Xilinx tools do not handle DDR-Less Design FSBL autogeneration correctly. To get around this problem manual modifications are necessary, see DDR less ZYNQ Design.
For this case, you can try the following steps without guarantee for success:
The easiest way to change the Boot Mode pinstrap is temporary connection of SPI Flash Pin 7 to ground. This pin connected with Pullup-Resistor to 3.3V, to set FPGA in Quad-SPI Mode. Shorting this Pin with GND will enable JTAG Boot Mode.
Connect Pin 7 to one of the GND Pins (Temporary during powerup). After startup, Pin 7 trace is used to program the Flash, so it must be floated (disconnected from ground).